{"id":1110,"date":"2018-08-02T13:29:00","date_gmt":"2018-08-02T11:29:00","guid":{"rendered":"http:\/\/www.microgels.rwth-aachen.de\/?p=1110"},"modified":"2020-01-08T14:43:05","modified_gmt":"2020-01-08T13:43:05","slug":"nanoscopic-visualization-of-cross%e2%80%90linking-density-in-polymer-networks-with-diarylethene-photoswitches","status":"publish","type":"post","link":"https:\/\/www.microgels.rwth-aachen.de\/?p=1110","title":{"rendered":"Nanoscopic visualization of cross\u2010linking density in polymer networks with diarylethene photoswitches"},"content":{"rendered":"\n<figure class=\"wp-block-image size-large\"><a href=\"http:\/\/www.microgels.rwth-aachen.de\/wp-content\/uploads\/2019\/12\/Siemes_anie_201807741.png\"><img loading=\"lazy\" decoding=\"async\" width=\"1024\" height=\"437\" src=\"http:\/\/www.microgels.rwth-aachen.de\/wp-content\/uploads\/2019\/12\/Siemes_anie_201807741-1024x437.png\" alt=\"\" class=\"wp-image-1111\" srcset=\"https:\/\/www.microgels.rwth-aachen.de\/wp-content\/uploads\/2019\/12\/Siemes_anie_201807741-1024x437.png 1024w, https:\/\/www.microgels.rwth-aachen.de\/wp-content\/uploads\/2019\/12\/Siemes_anie_201807741-300x128.png 300w, https:\/\/www.microgels.rwth-aachen.de\/wp-content\/uploads\/2019\/12\/Siemes_anie_201807741-768x328.png 768w, https:\/\/www.microgels.rwth-aachen.de\/wp-content\/uploads\/2019\/12\/Siemes_anie_201807741-1536x656.png 1536w, https:\/\/www.microgels.rwth-aachen.de\/wp-content\/uploads\/2019\/12\/Siemes_anie_201807741.png 1775w\" sizes=\"auto, (max-width: 1024px) 100vw, 1024px\" \/><\/a><\/figure>\n\n\n\n<p>The degree of crosslinking plays an essential role in understanding the correlation between structure and properties of microgels. A cross-linker containing a diarylethene photoswitch allowed us to determine the distribution of cross-linkers in a poly(<em>N<\/em>-isopropylacrylamide) microgel synthesized by precipitation polymerization. Its distribution is significantly different from the distribution of the overall polymer density as determined by static light scattering.<\/p>\n\n\n\n<p><em>E. Siemes, O. Nevskyi, D. Sysoiev, S. K. Turnhoff, A. Oppermann, T. Huhn, W. Richtering and D. W\u00f6ll<\/em><\/p>\n\n\n\n<p><em> Angew. Chem. Int. Ed.<\/em> 2018, <strong>57<\/strong>, DOI: <a href=\"http:\/\/dx.doi.org\/10.1002\/anie.201807741\">10.1002\/anie.201807741 <\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>The degree of crosslinking plays an essential role in understanding the correlation between structure and properties of microgels. A cross-linker<\/p>\n","protected":false},"author":1,"featured_media":1111,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"advgb_blocks_editor_width":"","advgb_blocks_columns_visual_guide":"","footnotes":""},"categories":[34],"tags":[],"class_list":["post-1110","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-highlights"],"author_meta":{"display_name":"sfb985_admin","author_link":"https:\/\/www.microgels.rwth-aachen.de\/?author=1"},"featured_img":"https:\/\/www.microgels.rwth-aachen.de\/wp-content\/uploads\/2019\/12\/Siemes_anie_201807741-300x128.png","coauthors":[],"tax_additional":{"categories":{"linked":["<a href=\"https:\/\/www.microgels.rwth-aachen.de\/?cat=34\" class=\"advgb-post-tax-term\">Highlights<\/a>"],"unlinked":["<span class=\"advgb-post-tax-term\">Highlights<\/span>"]}},"comment_count":"0","relative_dates":{"created":"Posted 8 years ago","modified":"Updated 6 years ago"},"absolute_dates":{"created":"Posted on August 2, 2018","modified":"Updated on January 8, 2020"},"absolute_dates_time":{"created":"Posted on August 2, 2018 13:29","modified":"Updated on January 8, 2020 14:43"},"featured_img_caption":"","series_order":"","_links":{"self":[{"href":"https:\/\/www.microgels.rwth-aachen.de\/index.php?rest_route=\/wp\/v2\/posts\/1110","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.microgels.rwth-aachen.de\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.microgels.rwth-aachen.de\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.microgels.rwth-aachen.de\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.microgels.rwth-aachen.de\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=1110"}],"version-history":[{"count":4,"href":"https:\/\/www.microgels.rwth-aachen.de\/index.php?rest_route=\/wp\/v2\/posts\/1110\/revisions"}],"predecessor-version":[{"id":1357,"href":"https:\/\/www.microgels.rwth-aachen.de\/index.php?rest_route=\/wp\/v2\/posts\/1110\/revisions\/1357"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.microgels.rwth-aachen.de\/index.php?rest_route=\/wp\/v2\/media\/1111"}],"wp:attachment":[{"href":"https:\/\/www.microgels.rwth-aachen.de\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=1110"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.microgels.rwth-aachen.de\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=1110"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.microgels.rwth-aachen.de\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=1110"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}